Yashasvi Jaiswal made a sparkling hundred and Washington Sundar a blistering fifty before Mohammed Siraj struck with the last ball of Saturday's play to bolster India's hopes of a series-levelling win in the fifth and deciding Test against England at the Oval.
India were dismissed for 396 in their second innings on the third day as they set England a target of 374 to win with just over two days' remaining.
Fast bowler Siraj, ever-present in all five matches of a gruelling series, yorked Zak Crawley for 14 with just two balls left to spark joyous celebrations among the tourists.
England were 50-1 at stumps, still requiring a further 324 runs to win, with Ben Duckett 34 not out.
No side have made more to win in the fourth innings of a Test at the Oval than England's 263 in a one-wicket victory over Australia back in 1902.
However, the most England have made to win any Test in the fourth innings was their 378 against India at Edgbaston in 2022, while they also chased down 371 at Headingley in the opening match of this series.
"It is a replay from Headingley," England fast bowler Josh Tongue, who took 5-125 on Saturday, told the BBC.
He added: "It will be a great day of cricket tomorrow and a great day for us if we get the runs. It (the pitch) is doing a bit. A few balls tonight jumped off a good length but if you get through the first hour who knows?"
Earlier, Jaiswal was out for 118, his second hundred of the series after the talented left-hander's ton at Headingley.
"I need to push, and I need to do well for my team," said Jaiswal. "I was constantly talking to myself and enjoying the pressure."
The 23-year-old opener received superb support from Akash Deep in a third-wicket partnership of 107, the paceman belying his status as a nightwatchman with an accomplished 66 -- his maiden Test fifty.
Ravindra Jadeja and Sundar, both fresh from hundreds in Manchester, each made 53, with Sundar launching a brutal assault after a depleted England took the new ball.
A wayward home team, a bowler down after Chris Woakes suffered a shoulder injury diving in the field on Thursday, harmed their own cause by dropping six catches in the innings, with Jaiswal reprieved three times.
India resumed Saturday on 75-2.
Deep, dropped in the slips by Crawley off Tongue on 21, went to fifty when he pulled Gus Atkinson for his ninth four.
But with India on the verge of batting through the morning session without losing a wicket, Deep fell to Jamie Overton.
GILL FALLS SHY OF GAVASKAR RECORD
Shubman Gill, who has enjoyed a remarkable first series as India captain, fell to the very first ball after lunch when lbw to Atkinson for 11.
His exit left Gill just 20 runs adrift of Sunil Gavaskar's longstanding record for the most runs by an Indian cricketer in a Test series of 774, set against the West Indies in 1971.
Gill compiled 754 runs at a superb average of 75, including four hundreds.
Jaiswal's quick single off Atkinson saw the elated batsman to a 127-ball century, including 12 fours and two sixes.
Jaiswal, dropped on 110 by Duckett at leg gully, was eventually dismissed when he ramped Tongue straight to deep backward point before Jadeja completed his fifth fifty of the series in 71 balls.
England took the new ball as soon as possible, with India 342-7 off 80 overs and promptly tried to bounce out Sundar in what proved to be an expensive ploy.
The left-hander responded with three superb sixes, including hoisting Tongue over fine leg and deep midwicket in the space of three balls.
Sundar then smashed two fours and a soaring six over midwicket off three successive Atkinson deliveries to complete a brilliant 39-ball fifty before he was last man out.
ENGLAND: Zak Crawley, Ben Duckett, Ollie Pope (capt), Joe Root, Harry Brook, Jacob Bethell, Jamie Smith (wkt), Chris Woakes, Gus Atkinson, Jamie Overton, Josh Tongue
INDIA: Yashasvi Jaiswal, KL Rahul, Sai Sudharsan, Shubman Gill (capt), Karun Nair, Ravindra Jadeja, Dhruv Jurel (wkt), Washington Sundar, Akash Deep, Prasidh Krishna, Mohammed Siraj